Material

Aluminum Nitride Ceramics

Aluminium nitride (AlN) occupies a unique niche among technical ceramics: it conducts heat like a metal while remaining an electrical insulator. With thermal conductivity of 170–200 W/m·K — comparable to…

Aluminium nitride (AlN) occupies a unique niche among technical ceramics: it conducts heat like a metal while remaining an electrical insulator. With thermal conductivity of 170–200 W/m·K — comparable to some aluminium alloys — and electrical resistivity exceeding 10¹⁴ Ω·cm, AlN is the material of choice for power-electronics substrates, LED heat sinks and RF packaging where heat must be removed without creating short circuits.

Its thermal expansion coefficient (4.5×10^−6/K) closely matches silicon, minimising thermomechanical stress on mounted dies. This combination of properties has made AlN indispensable in electric vehicles, 5G base stations, laser diodes and high-power inverters where conventional alumina substrates cannot keep up with heat flux.

Typical Properties

Indicative ranges — confirm grade and test conditions before design commitment.

PropertyIndicative Value
CompositionAluminium nitride
Density3.26 g/cm3
Vickers hardness1100-1200 HV
Flexural strength300-350 MPa
Fracture toughness2.5-3.5 MPa.m1/2
Max. service temperature1000 C
Thermal conductivity170-200 W/m.K
Thermal expansion (20-1000 C)4.5 x10-6/K
Potential Advantages

Highest thermal conductivity among electrically insulating ceramics; CTE matches silicon for low-stress die attachment; non-toxic alternative to beryllia (BeO); good strength at elevated temperature; excellent plasma resistance for semiconductor process equipment.

Design Considerations

AlN hydrolyses slowly in humid environments, forming a surface layer of aluminium hydroxide that degrades thermal performance — specify a protective coating or hermetic package for long-term service in damp conditions. Cost is significantly higher than alumina, so reserve AlN for applications where its thermal conductivity is genuinely required.

Limitations & Trade-offs

Moderate fracture toughness (2.5–3.5 MPa·m^1/2) makes it susceptible to mechanical damage during handling; surface hydrolysis in moisture requires protection; higher cost than Al₂O₃ or Si₃N₄ for equivalent volumes; limited availability in very large or complex shapes compared to alumina.